์˜ฅํ…Ÿ ๊ทœ์น™ - [ํ™”ํ•™๊ฒฐํ•ฉ1] ๋ฃจ์ด์Šค ๊ตฌ์กฐ์™€ ํŒ”์ „์ž ๊ทœ์น™ (์˜ฅํ…Ÿ๊ทœ์น™

๊ทœ์น™ ์˜ฅํ…Ÿ ์˜ฅํ…Ÿ๊ทœ์น™ ์ •์˜์™€

๊ทœ์น™ ์˜ฅํ…Ÿ ์˜ฅํ…Ÿ๊ทœ์น™ ์ •์˜์™€

ํ™•์žฅ๋œ ์˜ฅํ…Ÿ : ๋„ค์ด๋ฒ„ ๋ธ”๋กœ๊ทธ

๊ทœ์น™ ์˜ฅํ…Ÿ ํ™•์žฅ๋œ ์˜ฅํ…Ÿ

๊ทœ์น™ ์˜ฅํ…Ÿ ์ผ๋ฐ˜ํ™”ํ•™ ํ•„์ˆ˜์ด๋ก 

๊ทœ์น™ ์˜ฅํ…Ÿ #1 ์˜ฅํ…Ÿ๊ทœ์น™

๊ทœ์น™ ์˜ฅํ…Ÿ Octet rule

๊ทœ์น™ ์˜ฅํ…Ÿ ์ผ๋ฐ˜ํ™”ํ•™ ํ•„์ˆ˜์ด๋ก 

๊ทœ์น™ ์˜ฅํ…Ÿ Octet rule

๊ทœ์น™ ์˜ฅํ…Ÿ ํŒ”์ „์ž ๊ทœ์น™,

์˜ฅํ…Ÿ๊ทœ์น™ ์˜ˆ์™ธ์™€ ์œ„๋ฐ˜(violation of the octet rule) : ๋„ค์ด๋ฒ„ ๋ธ”๋กœ๊ทธ

๊ทœ์น™ ์˜ฅํ…Ÿ ํŒ”์ „์ž ๊ทœ์น™,

์˜ฅํ…Ÿ๊ทœ์น™ ์˜ˆ์™ธ์™€ ์œ„๋ฐ˜(violation of the octet rule) : ๋„ค์ด๋ฒ„ ๋ธ”๋กœ๊ทธ

2022.12.11 02:24:29

Octet rule

ํ˜•์‹ ์ „ํ•˜: ๊ฒฐํ•ฉ ์ „์ž๋ฅผ ๊ฐ ์›์ž์— ๊ณจ๊ณ ๋ฃจ ๋ฐฐ์น˜ํ•œ๋‹ค.

  • Housecroft, Catherine E.

  • ์ˆ˜์†Œ์˜ ๋“€์—ฃ๊ฒฐํ•ฉ์„ ์˜ฅํ…Ÿ๊ทœ์น™์œผ๋กœ ๋ณผ ์ˆ˜ ์žˆ๋ƒ? , John Wiley 1983 pp.

์˜ฅํ…Ÿ ๊ทœ์น™๊ณผ ์ฃผ๊ธฐ์œจํ‘œ

For , molecules tend to obey the which corresponds to the utilization of valence d, s and p orbitals to form bonding and non-bonding orbitals.

  • ๊ทธ๋ฆฌ๊ณ  ์ˆ˜์†Œ์™€ ํ—ฌ๋ฅจ์ฒ˜๋Ÿผ ์ฃผ์กฑ์›์†Œ์ž„์—๋„ ๋ถˆ๊ตฌํ•˜๊ณ  ์˜ฅํ…Ÿ๊ทœ์น™์— ์œ„๋ฐฐ๋˜๋Š” ๊ฒฝ์šฐ๊ฐ€ ๋‹ค์ˆ˜ ์กด์žฌํ•ฉ๋‹ˆ๋‹ค.

  • ์Œ์ด์˜จ์˜ ์ด๋ฆ„ ๋’ค์— ์–‘์ด์˜จ์˜ ์ด๋ฆ„์„ ๋ถ™์—ฌ ์ฝ๋Š”๋‹ค.

์›์†Œ ์ฃผ๊ธฐ์œจํ‘œ(๊ธฐ๋ณธ 20๊ฐœ์™€ ์ถ”๊ฐ€ 4๊ฐœ)/ ์˜ฅํ…Ÿ๊ทœ์น™(8์ „์ž ๊ทœ์น™)

๊ฒฝํ—˜์ ์ธ ๊ทœ์น™์ด๊ธฐ ๋•Œ๋ฌธ์— ๋ชจ๋“  ๋ฌผ์งˆ์ด ์˜ฅํ…Ÿ ๊ทœ์น™์— ์˜ํ•œ ์ „์ž๋ฐฐ์น˜๋ฅผ ๊ฐ€์ง€์ง€ ์•Š์Šต๋‹ˆ๋‹ค.

  • ๋”ฐ๋ผ์„œ ์ผ์‚ฐํ™”์งˆ์†Œ๋Š” ๋ถˆ์•ˆ์ •ํ•˜๋ฉฐ ํ•ด๋กœ์šด ๊ธฐ์ฒด์ž…๋‹ˆ๋‹ค.

  • The Chemical Bond: Chemical Bonding Across the Periodic Table.

[ํ™”ํ•™๊ฒฐํ•ฉ1] ๋ฃจ์ด์Šค ๊ตฌ์กฐ์™€ ํŒ”์ „์ž ๊ทœ์น™ (์˜ฅํ…Ÿ๊ทœ์น™

Magnusson, E.

  • ์˜ค๋Š˜์€ ์˜ฅํ…Ÿ๊ณผ ์ฃผ๊ธฐ์œจํ‘œ์—์„œ 1์กฑ๊ณผ 17์กฑ์— ๋Œ€ํ•ด ์•Œ์•„๋ณด์•˜์Šต๋‹ˆ๋‹ค.

  • ๋ถˆ์™„์ „ํ•œ ๊ทœ์น™์ด์—์š”.

ํŒ”์ „์ž ๊ทœ์น™, ์˜ฅํ…Ÿ ๊ทœ์น™(octet rule) โ˜…

์ด์™ธ์— Cds, Cus ๋“ฑ์„ ๊ฒ€์ถœํ•˜๊ธฐ๋„ ํ•˜๋Š”๋ฐ ์ด๋Š” ์ค‘๊ธˆ์†์ด๋ผ์„œ ์กด์žฌํ•˜๋ฉด ์•ˆ ๋˜๊ธฐ ๋•Œ๋ฌธ์— ๊ฒ€์ถœํ•˜๋Š” ๊ฒƒ์ž…๋‹ˆ๋‹ค.

  • [On the formation of molecules as a question of atomic structure].

  • ์ด๊ฒฝ์šฐ ์ค‘์‹ฌ์›์†Œ์˜ ์ „๊ธฐ์Œ์„ฑ๋„๋ณด๋‹ค ์ค‘์‹ฌ์›์†Œ ์ฃผ๋ณ€์˜ ์›์†Œ๋“ค์ด ์งˆ๋Ÿ‰์ˆ˜๋Š” ์ž‘์ง€๋งŒ ์ „๊ธฐ์Œ ์„ฑ๋„๊ฐ€ ๋” ํฝ๋‹ˆ๋‹ค.




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